Chemical elements
  Selenium
    Isotopes
    Energy
    Production
    Application
    Allotropy
    Colloidal
    Physical Properties
    Chemical Properties
      Hydrogen Selenide
      Selenium Fluorides
      Selenium Monochloride
      Selenium Tetrachloride
      Selenium Monobromide
      Selenium Tetrabromide
      Selenium Chlorobromides
      Selenium Oxyfluoride
      Selenium Oxychloride
      Sulphur Selenium Oxytetrachloride
      Selenium Oxybromide
      Chloroselenic Acid
      Selenium Dioxide
      Selenious Acid
      Selenium Trioxide
      Selenic Acid
      Selenates
      Perselenic Acid
      Selenium Sulphoxide
      Selenotrithionic Acid
      Diselenotrithionic Acid
      Selenopentathionic Acid
      Selenium Nitride
      Nitrosylselenic Acid
      Phosphorus Subselenide
      Phosphorus Monoselenide
      Tetraphosphorus Triselenide
      Phosphorus Triselenide
      Phosphorus Pentaselenide
      Phosphorus Chloroselenide
      Selenophosphates and Oxyselenophosphates
      Carbon Diselenide
      Carbon Subselenides
      Carbon Oxyselenide
      Carbon Sulphidoselenide
      Cyanogen Monoselenide
      Cyanogen Diselenide or Selenocyanogen
      Cyanogen Triselenide
      Selenocyanic Acid
      Ammonium Selenocyanate
      Caesium Triselenocyanate
      Copper Selenocyanate
      Lead Selenocyanate
      Magnesium Selenocyanate
      Mercurous Selenocyanate
      Mercuric Selenocyanate
      Potassium Selenocyanate
      Silver Selenocyanate
      Sodium Selenocyanate
      Zinc Selenocyanate
      Silicon Selenide
    Detection and Estimation

Silicon Selenide, SiSe2






When crystalline silicon is heated to a red heat in a current of dry hydrogen selenide reaction takes place with the formation of Silicon Selenide, SiSe2; the product is a dark, variegated mass, of metallic appearance, and has a very irritating odour. When heated to a dull red heat in a current of air or oxygen it undergoes oxidation with the formation of selenium, but the reaction is only superficial. Water reacts vigorously with the selenide with the production of silica and the liberation of hydrogen selenide. The silica forms a protective coating which hinders the total decomposition of the selenide. The reaction is more complete in the presence of caustic potash, which dissolves both the silica and the hydrogen selenide.


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